聚甲氧基二甲醚高温高压下喷雾燃烧特性光学诊断研究

Optical Study on spray and combustion characteristics of polymethoxy dimethyl ethers under high-temperature and highpressure conditions

来源:中文会议(科协)
中文摘要英文摘要

本文采用多种光学诊断方法,探究了聚甲氧基二甲醚PODE3 和PODE3-5 两种电力合成燃料在高温高压定容燃烧弹内的喷雾及燃烧特性. 此外,还应用正十二烷 (NC12)和混合燃料P50(50%PODE3、50%NC12,vol)作为参考燃料在相同的试验工况下也进行了测试. 试验过程中,采用高速纹影法获得了喷雾轮廓的演化过程和着火延迟期(ID),应用OH*化学荧光法测定了火焰浮起长度(LOL). 此外,利用平面激光诱导荧光技术获得了甲醛和OH*的瞬态演化过程. 最后,利用扩散背景光消光法(DBI)获得液相长度(LL)和火焰中的碳烟生成特性. 结果表明:PODE3-5 因为其较高的比热容和蒸发潜热需要更高的空气卷吸焓,相比较其他燃油具有明显较长的LL; 由于相近的十六烷值,所有燃油的ID 在所测环境工况下比较相似;由于PODE 燃油含氧量较高,化学计量比靠近喷雾轴心,导致两种PODE 燃料的OH*分布相对于NC12 更趋近喷雾轴心;PODE 燃料低温工况下甲醛大量形成,在LOL 附近的火焰中心出现剧烈释热现象;PODE 燃料由于不含C-C 键和喷雾中心的OH 分布,实验工况下未检测到碳烟生成,P50 相比较NC12 可显著减小稳态火焰中的碳烟量.

The ignition and combustion characteristics of two electric synthetic fuels, polymethoxydimethyl ether PODE3 and PODE3-5, were investigated in a high-temperature high-pressure combustion chamber by means of multiple optical diagnostics. In addition, ndodecane (NC12) and a blend fuel P50 (50% PODE3, 50% NC12, vol) were tested under the same operating conditions as references. During the test, the ignition delay (ID) and spray evolution were quantified using a high-speed Schlieren imaging technique. Meanwhile, the flame lift-off length (LOL) was determined by OH Chemiluminescence. In addition, the transient evolution of formaldehyde and OH were also obtained by means of planar laser induced fluorescence technique. Finally, the liquid length (LL) and the quantification of carbon soot generation were obtained thanks to the diffused back-illumination extinction imaging technique (DBI). The results show that PODE3-5 has significantly longer LL compared to other fuels because of its higher specific heat capacity and latent heat of evaporation requiring higher enthalpy of air coiling; the ID of all fuels are relatively similar under the measured ambient conditions due to similar cetane values; due to the higher oxygen content of PODE fuel, the stoichiometric ratio is close to the spray axis, resulting in the OH* distribution of the two PODE fuels being closer to the spray axis than NC12; formaldehyde is formed in large quantities in PODE fuel under low temperature conditions, and intense heat release occurs in the flame center near the LOL; PODE fuel does not contain C-C bonds and OH distribution in the spray center, so no carbon soot generation is detected under experimental conditions, P50 significantly reduces the amount of carbon soot in the steady-state flame compared to NC12.

李浩杰;玄铁民;王雨涛;常亚超;贾明;何志霞;王谦;

江苏大学 能源与动力工程学院,江苏 镇江 210203;江苏大学 能源与动力工程学院,江苏 镇江 210203;江苏大学 能源与动力工程学院,江苏 镇江 210203;大连理工大学 能源与动力工程学院,辽宁 大连,116024;大连理工大学 能源与动力工程学院,辽宁 大连,116024;江苏大学 能源研究院,江苏 镇江 210203;江苏大学 能源与动力工程学院,江苏 镇江 210203;

内燃动力碳中和与排放控制2023学术年会

聚甲氧基二甲醚 液相长度 火焰浮起长度 甲醛 碳烟

PODE liquid length flame lift-off length formaldehyde soot

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