U71Mn重轨钢中夹杂物表征
Characterization of inclusions in U71Mn heavy rail steel
非金属夹杂物是重轨钢内部损伤及产生疲劳破坏的主要原因。重轨钢采用无铝脱氧工艺,严格控制尖晶石类脆性夹杂物。本研究取自国内某钢厂常规工艺生产的一炉重轨钢,取中间包、连铸坯和成品钢轨研究钢中非金属夹杂物,基于自动电镜扫描与能谱结合分析了三个阶段夹杂物的形貌、平均成分、数量密度与面积分数的变化,发现Al2O3 夹杂成分变化幅度较大,占比由中间包的 64.81%上升至钢轨中 78.86%;SiO2由 16.80%降低到 2.57%;MnO由 4.65%降低到 1.76%;CaO由 9.46%下降到 4.64%;MgO由 4.28%上升至12.17%。钢轨中夹杂物的典型形貌为MnS包裹着氧化物的复合夹杂物,中包到钢轨过程中夹杂物数量密度逐渐下降,铸坯中由于凝固存在夹杂物析出和一些MnS包裹的氧化物导致面积分数和平均尺寸有所增加。
Non-metallic inclusions are the main cause of internal damage and fatigue failure of heavy rail steel.Heavy rail steel adopts aluminum-free deoxidation process and strictly controls spinel brittle inclusions.In this study,a furnace of heavy rail steel produced by a conventional process in a domestic steel mill was used to study the non-metallic inclusions in the steel from the tundish,continuous casting billet and finished rail.Based on the combination of automatic electron microscope scanning and energy spectrum,the morphology,average composition,number density and area fraction of inclusions in the three stages were analyzed.It was found that the composition of Al2O3 inclusions changed greatly,and the proportion increased from 64.81%in the tundish to 78.86%in the rail.SiO2 decreased from 16.80%to 2.57%.MnO decreased from 4.65%to 1.76%.CaO decreased from 9.46%to 4.64%.MgO increased from 4.28%to 12.17%.The typical morphology of inclusions in the rail is a composite inclusion of MnS wrapped with oxides.The number density of inclusions gradually decreases from the tundish to the rail,and the area fraction and average size of inclusions in the slab increase due to the precipitation of inclusions and some MnS wrapped oxides.
高梓淇;任强;张立峰;
燕山大学机械工程学院,秦皇岛 066044;燕山大学机械工程学院,秦皇岛 066044;北方工业大学机械与材料工程学院,北京 100144;
Heavy rail steel non-metallic inclusions inclusion characterization
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