压缩率对杨木重组木表面硬度的影响

Effect of compression ratios on the surface hardness of poplar wood scrimber

来源:中文会议(科协)
中文摘要英文摘要

[目的]以人工速生林杨木为研究材料,采用定向重组技术开发高硬度重组木,揭示压缩率对杨木重组木表面硬度的影响规律,以期为杨木的表面改性和重组木制备工艺的优化提供可靠的方法和科学依据。[方法]采用定向重组技术制备压缩率为 1.00、1.22 和 1.44 的三种杨木重组木,并以杨木、红榉和俄罗斯柞木作为对照样,采用万能力学试验机测定三种木材和三种不同压缩率杨木重组木样品表面的金氏硬度值;采用超景深三维显微镜、场发射扫描电镜观察样品表面的宏观和微观形貌,以及样品测试金氏硬度过程中破坏面的宏观和微观形貌;采用压汞法(MIP)测试样品孔隙率;采用激光共聚焦显微镜(LSCM)和透射电子显微镜(TEM)表征酚醛树脂在重组木内的分布情况。[结果]实验结果表明:杨木重组木的金氏硬度值随着压缩率的增大而增大。与杨木相比,压缩率为 1.44的重组木的金氏硬度值增加了 12.63倍,其硬度高于俄罗斯柞木和红榉的硬度。通过分析金氏硬度的应力应变曲线表明:压缩率越大,重组木的比例极限应力越大。通过扫描电镜和超景深显微镜观察可知:杨木原木的破坏面呈韧性断裂,而制备的重组木随着压缩率的增大其破坏模式逐渐变成脆性断裂。通过压汞法(MIP)测试样品孔隙率可知:定向重组显著降低了杨木的孔隙率,压缩率越大,重组木的孔隙率越低。通过激光共聚焦显微镜和透射电镜观察可知:随着压缩率的增加,树脂沿胶层带分布的宽度和深度逐渐增加,并且渗透到导管、木射线和纤维细胞的细胞腔中。重组木表面硬度的增大,主要是因为:杨木经过定向重组后,其导管和木纤维细胞被压缩密实,孔隙率降低,单位体积内的细胞实质密度增加,细胞之间的结合面积增大,连接更为紧密。同时,引入的PF树脂不仅将压缩的细胞结构固定,而且通过形成的胶钉,提高了细胞之间的连接强度,从而赋予重组木表面较高的硬度。[结论]定向重组技术可以有效解决速生人工林杨木材材质软、表面硬度低的问题,并且可通过控制压缩率调控重组木硬度,以满足不同应用场景对材料硬度的需求。

[Objective]In order to provide reliable methods and scientific basis for the modification of poplar wood surface and the optimization manufacturing process of wood scrimber,the directional recombination technology was applied to manufacture the wood scrimber of poplar with high-hardness,and then the effect of compression ratios(CR)on the surface hardness of wood scrimber was studied.[Method]The wood scrimber with compression ratios of 1.00,1.22 and 1.44 were prepared by the directional recombination technology,and the Poplar,Beech and Russian oak were taken as the control samples.The values of Janka hardness was measured by the universal mechanical testing machine.And the macroscopic and microscopic morphology of samples,as well as the damaged surface for samples during the testing process of Janka hardness were observed by ultra-depth-of-field three-dimensional microscope(UDTM)and field emission scanning electron microscope(SEM).Additionally,the porosity of the samples was tested by Mercury injection porosimetry(MIP)and distribution of Phenol-Formaldehyde resin(PF)within the wood scrimber was characterized by laser scanning confocal microscopy(LSCM)and transmission electron microscopy(TEM).[Result]The experimental results showed that the Janka hardness values of wood scrimber increased with increasing compression ratios.The Janka hardness value of wood scrimber with compression ratio of 1.44 increased by 12.63 times compared with that of poplar wood.Furthermore,the Janka hardness value of wood scrimber was much higher than those of Russian oak and Beech.In practical applications,the appropriate compression ratio of the wood scrimber can be determined according to the needs in different area.The analysis of stress-strain curve of Janka hardness showed that the proportional ultimate stress of wood scrimber increased with increasing compression ratio.The observation of SEM and UDTM revealed that the failure surface of poplar wood was ductile fracture,but changed to brittle fracture for the wood scrimber.The porosity of the samples tested by MIP showed that directed recombination technology significantly reduced the porosity of poplar wood,and the porosity of the wood scrimber decreased with increasing compression ratio.The observation of LSCM and TEM showed that the width and depth of PF resin distributed along the glue layer band gradually increased with increasing compression ratio and penetrated into the vessel,wood rays and fiber cells.The reasons for the increase in surface hardness of wood scrimber were as following:In the manufacturing process,the vessels and fiber cells of poplar wood were compressed,and the porosity of wood scrimber was reduced.Therefore,the parenchymal density of wood cells in per unit volume was increased.Additionally,the binding area between the wood cells is increased and the connections are tighter.Meanwhile,the PF not only fixed the compressed cell structure,but also increases the strength of the connection between the wood cells through the formed glue nails,which effectively improved the surface hardness of the wood scrimber.[Conclusion]The directional recombination technology can be applied to solve the soft problem and low surface hardness of poplar wood,and the surface hardness of the wood scrimber can be adjusted through the compression ratio,so that the products prepared by the directional recombination technology can meet the needs of different applications.

贺颖奇;卢勤;张亚梅;余养伦;于文吉;

中国林业科学研究院木材工业研究所,北京 100091;洪雅竹元科技有限公司,四川洪雅 620366;中国林业科学研究院木材工业研究所,北京 100091;中国林业科学研究院木材工业研究所,北京 100091;中国林业科学研究院木材工业研究所,北京 100091;

第八届中国林业学术大会

速生杨木 定向重组 压缩率 硬度 重组木

Fast-growing poplar wood directional reorganization compression ratio hardness wood scrimber

2572-2582 / 11

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